丁香油酚
外观
(重定向自丁子香酚)
丁香油酚 | |
---|---|
IUPAC名 4-烯丙基-2-甲氧基苯酚 | |
英文名 | Eugenol |
别名 | 甲氧基-4-(2-丙烯基)苯酚 2-甲氧基-4-丙烯基苯基苯乙醚 丁香油酚 丁子香酚 丁子香酸 烯丙基甲氧基苯酚 异丁香酚苯乙醚 |
识别 | |
CAS号 | 97-53-0 |
PubChem | 12636 |
ChemSpider | 13876103 |
SMILES |
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InChI |
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InChIKey | RRAFCDWBNXTKKO-UHFFFAOYAJ |
ChEBI | 4917 |
KEGG | D04117 |
性质 | |
化学式 | C10H12O2 |
摩尔质量 | 164.20 g·mol⁻¹ |
密度 | 1.06 g/cm3 |
熔点 | −9 °C(264 K) |
沸点 | 256 °C(529 K) |
危险性 | |
欧盟危险性符号 [1] | |
警示术语 | R:R22, R36/37/38, R38, R40, R42/43[1] |
安全术语 | S:S23, S24/25, S26, S36[1] |
闪点 | 104℃ |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
丁香油酚(英語:Eugenol,分子式C10H12O2),是一種有機化合物,存在於多種植物中,富含于其精油中,如月桂油等[1][2]。具有持久香氣,常作为香皂的香料。
丁香油酚是苯基丙烯,烯丙基鏈取代的鄰甲氧基苯酚。丁香油酚是苯丙類化合物中的一員。它是一種無色至淡黃色油狀液體,從特別是在丁香油、肉荳蔻、肉桂、羅勒和月桂葉某些精油提取。它存在於丁香花蕾油中80-90%的濃度,在丁香葉油82-88%的濃度。
丁香油酚的英文名字“eugenol”源自丁香其中一个属名——“Eugenia”(番樱桃属)。丁香的香氣主要來自其中的丁香油酚。
性質
[编辑]物理性質
[编辑]化學性質
[编辑]製備
[编辑]用途
[编辑]危害
[编辑]含有丁香油酚的植物
[编辑]參見
[编辑]參考文獻
[编辑]- ^ 1.0 1.1 1.2 1.3 1.4 1.5 (中文)ChemicalBook 丁香油酚 (页面存档备份,存于互联网档案馆)
- ^ Peter William Atkins. 第4章 味覺、嗅覺和痛覺. 化學分子世界導覽一. 天下文化. 2010: 211. ISBN 978-986-216-220-0.
- ^ 化工词典 丁香油酚. [2011-05-20]. (原始内容存档于2011-10-24).
- ^ 4.0 4.1 (中文)丁香油酚的药理作用 (页面存档备份,存于互联网档案馆)
- ^ 「麻醉魚」是怎麼回事? | 科學人 | 果殼網 科技有意思. [2014-08-15]. (原始内容存档于2015-04-15).
- ^ 丁香油麻醉魚? 魚市場保全:行之有年. [2014-08-15]. (原始内容存档于2014-08-15).
- ^ 北京最大海鲜市场用麻醉药喂鱼 商人称为卖相好. [2014-08-15]. (原始内容存档于2016-02-23).
- ^ Eugenol Oil Overdose (页面存档备份,存于互联网档案馆), New York Times Health Guide
- ^ Hartnoll, G; Moore, D; Douek, D. Near fatal ingestion of oil of cloves.. Archives of disease in childhood. 1993, 69 (3): 392–3. PMC 1029532 . PMID 8215554. doi:10.1136/adc.69.3.392.
- ^ Thompson, DC; Barhoumi, R; Burghardt, RC. Comparative toxicity of eugenol and its quinone methide metabolite in cultured liver cells using kinetic fluorescence bioassays.. Toxicology and applied pharmacology. 1998, 149 (1): 55–63. PMID 9512727. doi:10.1006/taap.1997.8348.
- ^ Fujisawa, S; Atsumi, T; Kadoma, Y; Sakagami, H. Antioxidant and prooxidant action of eugenol-related compounds and their cytotoxicity.. Toxicology. 2002, 177 (1): 39–54. PMID 12126794. doi:10.1016/S0300-483X(02)00194-4.
- ^ Pathak, S. B.; Niranjan, K.; Padh, H.; Rajani, M.; et al. TLC Densitometric Method for the Quantification of Eugenol and Gallic Acid in Clove. Chromatographia. 2004, 60 (3 - 4): 241–244. doi:10.1365/s10337-004-0373-y.
- ^ 13.0 13.1 BULLERMAN, L. B.; Lieu, F. Y.; Seier, Sally A.; et al. INHIBITION OF GROWTH AND AFLATOXIN PRODUCTION BY CINNAMON AND CLOVE OILS. CINNAMIC ALDEHYDE AND EUGENOL. Journal of Food Science. 1977, 42 (4): 1107–1109. doi:10.1111/j.1365-2621.1977.tb12677.x.
- ^ Lee, Kwang-Geun; Takayuki Shibamoto. Antioxidant property of aroma extract isolated from clove buds [Syzygium aromaticum (L.) Merr. et Perry]. Food Chemistry. 2001, 74 (4): 443–448 [3 July 2009]. doi:10.1016/S0308-8146(01)00161-3.
- ^ Kreydiyyeh, S. I.; Usta, J; Copti, R; et al. Effect of cinnamon, clove and some of their constituents on the Na+-K+-ATPase activity and alanine absorption in the rat jejunum. Food and Chemical Toxicology. 2000, 38 (9): 755–762 [3 July 2009]. PMID 10930696. doi:10.1016/S0278-6915(00)00073-9.
- ^ Dighe, V. V.; Gursale, A. A.; Sane, R. T.; Menon, S.; Patel, P. H.; et al. Quantitative Determination of Eugenol from Cinnamomum tamala Nees and Eberm. Leaf Powder and Polyherbal Formulation Using Reverse Phase Liquid Chromatography. Chromatographia. 2005, 61 (9 - 10): 443–446. doi:10.1365/s10337-005-0527-6.
- ^ Bennett, A.; Stamford, I. F.; Tavares, I. A.; Jacobs, S.; Capasso, F.; Mascolo, N.; Autore, G.; Romano, V.; Di Carlo, G.; et al. The biological activity of eugenol, a major constituent of nutmeg (Myristica fragrans): Studies on prostaglandins, the intestine and other tissues. Phytotherapy Research. 1988, 2 (3): 124–130. doi:10.1002/ptr.2650020305.
- ^ Johnson, C. B.; Kirby, J.; Naxakis, G.; Pearson, S. Substantial UV-B-mediated induction of essential oils in sweet basil (Ocimum basilicum L.). Phytochemistry. 1999, 51 (4): 507–510 [24 November 2009]. doi:10.1016/S0031-9422(98)00767-5.
- ^ Celso Vataru Nakamura, Tania Ueda-Nakamura, Erika Bando, Abrahão Fernandes Negrão Melo, Díogenes Aparício Garcia Cortez, Benedito Prado Dias Filho, "Antibacterial Activity of Ocimum gratissimum L. Essential Oil", Memórias do Instituto Oswaldo Cruz, Vol. 94(5): 675-678.. [2011-05-18]. (原始内容存档于2012-10-09).
- ^ Lemon balm. University of Maryland Medical Center. [2010-12-07]. (原始内容存档于2013-05-22).
外部連結
[编辑]
- (英文)Kegley, S.E., Hill, B.R., Orme S., Choi A.H., Toxicity Information for Eugenol(页面存档备份,存于互联网档案馆) in PAN Pesticide Database, Pesticide Action Network, North America (San Francisco, CA, 2010)
- (英文)Eugenol (Mmm, dentist) : Molecule of the Day. ScienceBlogs. 2006-10-04 [2010-12-07]. (原始内容存档于2009-12-30). (Eugenol entry on the Molecule of the Day blog)
- 丁子香酚 Eugenol (页面存档备份,存于互联网档案馆) 中草藥化學圖像數據庫 (香港浸會大學中醫藥學院) (中文)(英文)