二碘合银酸二(1,3-二氢-1,3-二甲基咪唑-2-亚基)银

二碘合银酸二(1,3-二氢-1,3-二甲基咪唑-2-亚基)银
识别
CAS号	1000064-48-1
SMILES	[I-][Ag+][I-].[Ag+5](=[C-2]1N(C=CN1C)C)=[C-2]2N(C=CN2C)C;
性质
化学式	C10H16Ag2I2N4
摩尔质量	661.81 g·mol−1
外观	白色固体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

二碘合银酸二(1,3-二氢-1,3-二甲基咪唑-2-亚基)银是一种配位化合物，化学式为[C₁₀H₁₆AgN₄][AgI₂]。它可由1,3-二甲基咪唑鎓碘化物和氧化银于二氯甲烷中反应制得。^[2]^[1]它和金属铕反应，可以得到二碘化四(1,3-二氢-1,3-二甲基咪唑-2-亚基)铕。^[3]

参考文献

^ ^1.0 ^1.1 Joseph M. Meredith; et al. C–H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study. Organometallics 2012, 31, 5, 1879–1887. doi:10.1021/om2012166.
^ Dorette S. Tromp; et al. Synthesis of bis-N-alkyl imidazolium salts and their palladium(0)(NHC)(η2-MA)2 complexes. Appl. Organomet. Chem. 2012. 26 (7). doi:10.1002/aoc.2866.
^ Noah Schwarz; et al. Application of the Redox-Transmetalation Procedure to Access Divalent Lanthanide and Alkaline-Earth NHC Complexes. Chemistry A European Journal. 2021. 27 (5). 12857-12865. doi:10.1002/chem.202101923.

[Joseph-1] 1.0 ^1.1 Joseph M. Meredith; et al. C–H Bond Activation by Cationic Iridium(III) NHC Complexes: A Combined Experimental and Computational Study. Organometallics 2012, 31, 5, 1879–1887. doi:10.1021/om2012166.

[2] Dorette S. Tromp; et al. Synthesis of bis-N-alkyl imidazolium salts and their palladium(0)(NHC)(η2-MA)2 complexes. Appl. Organomet. Chem. 2012. 26 (7). doi:10.1002/aoc.2866.

[3] Noah Schwarz; et al. Application of the Redox-Transmetalation Procedure to Access Divalent Lanthanide and Alkaline-Earth NHC Complexes. Chemistry A European Journal. 2021. 27 (5). 12857-12865. doi:10.1002/chem.202101923.

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