对苯二甲酰氯
| 对苯二甲酰氯 | |
|---|---|
| |
| |
| IUPAC名 Benzene-1,4-dicarbonyl dichloride[1] | |
| 别名 | Terephthaloyl dichloride[1] 1,4-Benzenedicarbonyl chloride Benzene-1,4-dicarbonyl chloride Terephthalic acid dichloride Terephthaloyl dichloride p-Phthalyl chloride TCL |
| 识别 | |
| CAS号 | 100-20-9 
|
| PubChem | 7488 |
| ChemSpider | 7207 |
| SMILES |
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| InChI |
|
| InChIKey | LXEJRKJRKIFVNY-UHFFFAOYAY |
| 性质 | |
| 化学式 | C8H4Cl2O2 |
| 摩尔质量 | 203.02 g/mol g·mol⁻¹ |
| 密度 | 1.34 g/cm3 |
| 熔点 | 80—82 °C（353—355 K）[2] |
| 沸点 | 265 °C（538 K） |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
对苯二甲酰氯是一种有机化合物，化学式为C8H4Cl2O2。它可由对苯二甲酸和氯化亚砜在N,N-二甲基甲酰胺（或N,N-二甲基乙酰胺[3]）的催化下回流反应得到。[4]它在三氯化铝的催化下和苯反应，生成1,4-二苯甲酰基苯。[5]
参考文献
[编辑]- ^ 1.0 1.1 Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge: The Royal Society of Chemistry. 2014: 797. ISBN 978-0-85404-182-4. doi:10.1039/9781849733069-FP001.
- ^ Phthaloyl chlorides. 1950 GB 644071
- ^ Bhim Bali Prasad, Darshika Jauhari. A dual-template biomimetic molecularly imprinted dendrimer-based piezoelectric sensor for ultratrace analysis of organochlorine pesticides. Sensors and Actuators B: Chemical. 2015-02, 207: 542–551 [2019-11-07]. doi:10.1016/j.snb.2014.10.115. （原始内容存档于2018-06-24） （英语）.
- ^ Subrata Nath, Suraj Kumar Pathak, Joydip De, Santanu Kumar Pal, Ammathnadu S. Achalkumar. Star-shaped π-gelators based on oxadiazole and thiadiazoles: a structure–property correlation. Molecular Systems Design & Engineering. 2017, 2 (4): 478–489 [2019-11-07]. ISSN 2058-9689. doi:10.1039/C7ME00040E （英语）.
- ^ Theodore A. Gazis, Ayan Dasgupta, Michael S. Hill, Jeremy M. Rawson, Thomas Wirth, Rebecca L. Melen. Reactions of hydrazones and hydrazides with Lewis acidic boranes. Dalton Transactions. 2019, 48 (33): 12391–12395 [2019-11-07]. ISSN 1477-9226. doi:10.1039/C9DT01359H （英语）.