苯并[c]芴
| 苯并[c]芴 | |
|---|---|
| |
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| |
| IUPAC名 7H-Benzo[c]fluorene | |
| 英文名 | Benzo[c]fluorene |
| 别名 | 7H-苯并[c]芴 |
| 识别 | |
| CAS号 | 205-12-9 
|
| PubChem | 915 |
| ChemSpider | 8796 |
| ChEBI | 82403 |
| KEGG | C19344 |
| 性质 | |
| 化学式 | C17H12 |
| 摩尔质量 | 216.28 g·mol−1 |
| 外观 | 白色固体[1] |
| 密度 | 1.185 g/cm3 |
| 熔点 | 125-127 °C[2] 121-123 °C[3] |
| 沸点 | 398.3±12.0 °C[4] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
苯并[c]芴是一种稠环芳香烃，化学式为C17H12。它是煤焦油和香烟燃烧的烟的组成部分，被认为是其致癌的主要因素。
它可由1-(2-溴苯基)萘和三甲基硅基重氮甲烷为原料在四(三苯基膦)钯催化下反应制得[1]，或由1-(2-氯甲基苯基)萘和碳酸铯在催化反应得到[3]。
参考文献
[编辑]- ^ 1.0 1.1 Xu, Shuai; Chen, Ri; Fu, Zihao; Zhou, Qi; Zhang, Yan; Wang, Jianbo. Palladium-Catalyzed Formal [4 + 1] Annulation via Metal Carbene Migratory Insertion and C(sp 2 )–H Bond Functionalization. ACS Catalysis. 2017-03-03, 7 (3): 1993–1997. doi:10.1021/acscatal.6b03562.
- ^ Cristol, Stanley J.; Vanden Plas, Bart J. Photochemical transformations. 47. Direct irradiation in acetic acid of 1-(bromomethyl)dibenzosemibullvalene [1-bromomethyl-3,4:6.7-dibenzotricyclo[3.3.0.02,8]octa-3,6-diene]. The Journal of Organic Chemistry (American Chemical Society (ACS)). 1989, 54 (5): 1209–1211. ISSN 0022-3263. doi:10.1021/jo00266a043.
- ^ 3.0 3.1 Hwang, Seung Jun; Kim, Hyun Jin; Chang, Sukbok. Highly Efficient and Versatile Synthesis of Polyarylfluorenes via Pd-Catalyzed C−H Bond Activation. Organic Letters. 2009-10-15, 11 (20): 4588–4591. doi:10.1021/ol901854f.
- ^ Calculated using Advanced Chemistry Development (ACD/Labs) Software V11.02 (© 1994-2023 ACD/Labs). Retrieved from SciFinder. [2023-09-26].