1-十六醛

1-十六醛
	IUPAC名; hexadecanal
别名	Hexadecanal; AI3-24252; EINECS 211-111-0; UNII-WQD27655QE
识别
CAS号	629-80-1
PubChem	984
ChemSpider	959
SMILES	CCCCCCCCCCCCCCCC=O;
InChI	1S/C16H32O/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h16H,2-15H2,1H3;
InChIKey	NIOYUNMRJMEDGI-UHFFFAOYSA-N
EINECS	211-111-0
ChEBI	17600
KEGG	C00517
性质
化学式	C16H32O
摩尔质量	240.42 g·mol−1
熔点	34—35 °C（307—308 K）
沸点	160—162 °C（433—435 K）（13 torr）
溶解性（水）	难溶
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

1-十六醛是一种有机化合物，属于醛类，化学式为C₁₆H₃₂O。它可由吡啶氯铬酸盐氧化1-十六烷醇制得。^[3]镁-氯化亚锡试剂又可将其还原为醇。^[4]它和溴乙酸乙酯在锌、盐酸存在下反应，可以得到3-羟基十八酸乙酯；^[5]3,3-二氟-3-溴丙烯和铟可以与之发生相似反应，生成3,3-二氟十九碳-1-烯-4-醇。^[6]

参考文献

^ Gordeev, K. Yu.; Serebrennikova, G. A.; Evstigneeva, R. P. Use of anionites in the tetrahydroborate form for obtaining higher liquid aldehydes. Zhurnal Organicheskoi Khimii, 1985. 21 (12): 2615-2616. ISSN 0514-7492
^ Enzo Santaniello, Fulvia Milani, Rosangela Casati. Tetrabutylammonium Chlorochromate, A New Mild and Selective Oxidizing Agent. Synthesis. 1983, 1983 (09): 749–751 [2021-11-23]. ISSN 0039-7881. doi:10.1055/s-1983-30500. （原始内容存档于2018-06-07）（英语）.
^ Thomas W. Bevan, James Francis-Taylor, Helena Wong, Peter T. Northcote, Joanne E. Harvey. A colourful azulene-based protecting group for carboxylic acids. Tetrahedron. 2018-06, 74 (24): 2942–2955 [2021-11-23]. doi:10.1016/j.tet.2018.04.066 （英语）.
^ Manobjyoti Bordoloi, Ram P Sharmat, Vaishali Chakraborty. Magnesium-Tin(II) Chloride Dihydrate: A New System for Chemoselective Reduction of Aldehydes into Alcohols in the Presence of Ketones, Ketalization of Ketones and Dehalogenation of Benzyl Halides. Synthetic Communications. 1999-07, 29 (14): 2501–2506 [2021-11-23]. ISSN 0039-7911. doi:10.1080/00397919908086257 （英语）.
^ Jenny, E. F.; Grob, C. A. The synthesis of erythro-dihydrosphingosine from trans-2-octadecenoic acid. Helvetica Chimica Acta, 1953. 36: 1936-1944. ISSN 0018-019X.
^ Hikaru Yanai, Haruna Okada, Azusa Sato, Midori Okada, Takeo Taguchi. Copper-free defluorinative alkylation of allylic difluorides through Lewis acid-mediated C–F bond activation. Tetrahedron Letters. 2011-06, 52 (23): 2997–3000 [2021-11-23]. doi:10.1016/j.tetlet.2011.03.148. （原始内容存档于2018-06-25）（英语）.

[1] Gordeev, K. Yu.; Serebrennikova, G. A.; Evstigneeva, R. P. Use of anionites in the tetrahydroborate form for obtaining higher liquid aldehydes. Zhurnal Organicheskoi Khimii, 1985. 21 (12): 2615-2616. ISSN 0514-7492

[2] Enzo Santaniello, Fulvia Milani, Rosangela Casati. Tetrabutylammonium Chlorochromate, A New Mild and Selective Oxidizing Agent. Synthesis. 1983, 1983 (09): 749–751 [2021-11-23]. ISSN 0039-7881. doi:10.1055/s-1983-30500. （原始内容存档于2018-06-07）（英语）.

[3] Thomas W. Bevan, James Francis-Taylor, Helena Wong, Peter T. Northcote, Joanne E. Harvey. A colourful azulene-based protecting group for carboxylic acids. Tetrahedron. 2018-06, 74 (24): 2942–2955 [2021-11-23]. doi:10.1016/j.tet.2018.04.066 （英语）.

[4] Manobjyoti Bordoloi, Ram P Sharmat, Vaishali Chakraborty. Magnesium-Tin(II) Chloride Dihydrate: A New System for Chemoselective Reduction of Aldehydes into Alcohols in the Presence of Ketones, Ketalization of Ketones and Dehalogenation of Benzyl Halides. Synthetic Communications. 1999-07, 29 (14): 2501–2506 [2021-11-23]. ISSN 0039-7911. doi:10.1080/00397919908086257 （英语）.

[5] Jenny, E. F.; Grob, C. A. The synthesis of erythro-dihydrosphingosine from trans-2-octadecenoic acid. Helvetica Chimica Acta, 1953. 36: 1936-1944. ISSN 0018-019X.

[6] Hikaru Yanai, Haruna Okada, Azusa Sato, Midori Okada, Takeo Taguchi. Copper-free defluorinative alkylation of allylic difluorides through Lewis acid-mediated C–F bond activation. Tetrahedron Letters. 2011-06, 52 (23): 2997–3000 [2021-11-23]. doi:10.1016/j.tetlet.2011.03.148. （原始内容存档于2018-06-25）（英语）.

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