2,5-环己二烯-1,4-二亚胺
| 2,5-环己二烯-1,4-二亚胺 | |
|---|---|
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| 别名 | 对苯醌二亚胺 PDI |
| 识别 | |
| CAS号 | 4377-73-5 
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| SMILES |
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| 性质 | |
| 化学式 | C6H6N2 |
| 摩尔质量 | 106.13 g·mol−1 |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
2,5-环己二烯-1,4-二亚胺是一种有机化合物，化学式为C6H6N2。它可由对苯二胺经化学[1]或电化学[2]氧化得到：
- H2NC6H4NH2 ⇌ HN=C6H4=NH + 2 H+ + 2 e−
它可以和间苯二酚发生偶合反应，生成4-(4-氨基苯胺基)-1,3-苯二酚。[1]
参考文献
[编辑]- ^ 1.0 1.1 Aaron D. Bailey; Bryan P. Murphy; and Hairong Guan. Mechanistic Insights into Oxidative Oligomerization of p-Phenylenediamine and Resorcinol. J. Phys. Chem. A 2016, 120, 43, 8512–8520. doi:10.1021/acs.jpca.6b08571.
- ^ Sarawudh Nathabumroong, Chatwarin Poochai, Johannes Philipp Mensing, Chakrit Sriprachuabwong, Jaruwit Lohitkarn, Tanom Lomas, Rattikorn Yimnirun, and Adisorn Tuantranont. Violet Laser Treatment of Nitrogen-Doped Reduced Graphene Oxide Electrodes and KOH Electrolytes Containing p-Phenylenediamine for High-Performance Supercapacitors. ACS Appl. Nano Mater. 2023, 6, 1, 34–43. doi:10.1021/acsanm.2c03373.
延伸阅读
[编辑]- Nobuyuki Akai, Satoshi Kudoh, and Munetaka Nakata. UV Photolysis of 1,4-Diaminobenzene in a Low-Temperature Argon Matrix to 2,5-Cyclohexadiene-1,4-diimine via 4-Aminoanilino Radical. J. Phys. Chem. A 2003, 107, 34, 6725–6730. doi:10.1021/jp022694z.