3,4-环氧环己烷甲酸甲酯
| 3,4-环氧环己烷甲酸甲酯 | |
|---|---|
| |
| IUPAC名 Methyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate | |
| 识别 | |
| CAS号 | 41088-52-2 |
| PubChem | 12770164 |
| ChemSpider | 11227215 |
| SMILES |
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| 性质 | |
| 化学式 | C8H12O3 |
| 摩尔质量 | 156.18 g·mol−1 |
| 外观 | 无色液体[1] |
| 沸点 | 109.5—110.5 °C（382.6—383.6 K）（17 mmHg）[2] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
3,4-环氧环己烷甲酸甲酯是一种环氧化物，化学式为C8H12O3，可用于制备用于生产交联环氧树脂。[3][4]它本身在均聚时会产生线形聚合物。
制备及性质
[编辑]3,4-环氧环己烷甲酸甲酯可由4-环己烯甲酸甲酯与过酸进行环氧化反应得到。[3]
参考文献
[编辑]- ^ James V. Crivello, Ulrike Varlemann. Mechanistic study of the reactivity of 3,4-epoxycyclohexylmethyl 3′,4′-epoxycyclohexancarboxylate in photoinitiated cationic polymerizations. Journal of Polymer Science Part A: Polymer Chemistry. October 1995, 33 (14): 2473–2486. doi:10.1002/pola.1995.080331421.
- ^ NORMAN A. NELSON , GEORGE A. MORTIMER. Bicyclo[3.1.0]hexane Derivatives. I. Synthesis of Bicyclo[3.1.0]-2-hexanone and Methyl Bicyclo[3.1.0]hexane-1-carboxylate. The Journal of Organic Chemistry. October 1957, 22 (10): 1146–1153. doi:10.1021/jo01361a003.
- ^ 3.0 3.1 3.2 Pham, Ha Q.; Marks, Maurice J. Epoxy Resins. Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a09_547.pub2.
- ^ US 6201070 "METHOD FOR ENHANCING THE TOUGHNESS OF CYCLOALIPHATIC EPOXIDE-BASED COATINGS."