3-(2-乙基己氧基)-1,2-丙二醇
| 3-(2-乙基己氧基)-1,2-丙二醇 | |
|---|---|
| |
| 别名 | 乙基己基甘油 辛氧基甘油 甘油单异辛基醚 |
| 识别 | |
| CAS号 | 70445-33-9 
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| PubChem | 9859093 |
| 性质 | |
| 化学式 | C11H24O3 |
| 摩尔质量 | 204.31 g·mol⁻¹ |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
3-(2-乙基己氧基)-1,2-丙二醇是一种有机化合物，化学式为C11H24O3。它可由丙三醇、2-乙基己酸和氢气在钯催化下反应制得；[1]或由异辛基缩水甘油醚在对甲苯磺酸催化下水解得到。[2]它和硫酸二甲酯或磷酸三甲酯在一定条件下反应，可以得到3-[(2,3-二甲氧基丙氧基)甲基]庚烷。[1][3]
参考文献
[编辑]- ^ 1.0 1.1 Marc Sutter, Wissam Dayoub, Estelle Métay, Yann Raoul, Marc Lemaire. 1,2,3-Trimethoxypropane and Glycerol Ethers as Bio-Sourced Solvents from Glycerol. Synthesis by Solvent-Free Phase-Transfer Catalysis and Utilization as an Alternative Solvent in Chemical Transformations. ChemCatChem. 2013-10, 5 (10): 2893–2904 [2021-11-18]. doi:10.1002/cctc.201300458 （英语）.
- ^ Shirasawa, Takeshi; Oka, Hiroshi; Morishita, Mitsugu; Okutsu, Munenao. Preparation of glyceryl ethers by hydrolysis of glycidyl ethers with decreased loss of water. 2003. JP 2003267901 A.
- ^ Marie‐Christine Duclos, Aurélien Herbinski, Anne‐Sophie Mora, Estelle Métay, Marc Lemaire. Methylation of Polyols with Trimethylphosphate in the Presence of a Lewis or Brønsted Acid Catalyst. ChemSusChem. 2018-02-09, 11 (3): 547–551 [2021-11-18]. ISSN 1864-5631. doi:10.1002/cssc.201701841 （英语）.