N-甲酰基四氢吡咯
| N-甲酰基四氢吡咯 | |
|---|---|
| |
| 别名 | 1-吡咯甲醛 |
| 识别 | |
| CAS号 | 3760-54-1 
|
| 性质 | |
| 化学式 | C5H9NO |
| 摩尔质量 | 99.13 g·mol−1 |
| 密度 | 1.0409 g·cm−3（20 °C）[1] |
| 沸点 | 213—214 °C（486—487 K）[1] |
| 若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。 | |
N-甲酰基四氢吡咯是一种有机化合物，化学式为C5H9NO。它可由四氢吡咯和二氧化碳在还原剂二甲胺-甲硼烷（Me2NH·BH3）的存在下反应制得；[2]四氢吡咯和一氧化碳[3]或二甲基甲酰胺[4]反应也能得到N-甲酰基四氢吡咯。在催化剂的存在下，它可以被还原为N-甲基四氢吡咯。[5]
参考文献
[编辑]- ^ 1.0 1.1 Komori, Saburo; Okahara, Mitsuo; Shinsugi, Ei. Synthesis of fatty acid sucrose esters with new solvents. Technology Reports of the Osaka University, 1958. 8: 497-506. ISSN: 0030-6177.
- ^ Vishal V. Phatake, Ashish A. Mishra, Bhalchandra M. Bhanage. UiO-66 as an efficient catalyst for N-formylation of amines with CO2 and dimethylamine borane as a reducing agent. Inorganica Chimica Acta. 2020-02, 501: 119274 [2020-12-29]. doi:10.1016/j.ica.2019.119274 （英语）.
- ^ Young Jin Kim, Ji Woo Lee, Hyun Ji Lee, Shuyao Zhang, Je Seung Lee, Minserk Cheong, Hoon Sik Kim. K3PO4-catalyzed carbonylation of amines to formamides. Applied Catalysis A: General. 2015-10, 506: 126–133 [2020-12-29]. doi:10.1016/j.apcata.2015.09.004. （原始内容存档于2018-06-21） （英语）.
- ^ Kyoko Takahashi, Makoto Shibagaki, Hajime Matsushita. Formylation of Amines by Dimethylformamide in the Presence of Hydrous Zirconium Oxide. Agricultural and Biological Chemistry. 1988-03, 52 (3): 853–854 [2020-12-29]. ISSN 0002-1369. doi:10.1080/00021369.1988.10868711.
- ^ Mario Stein, Bernhard Breit. Catalytic Hydrogenation of Amides to Amines under Mild Conditions. Angewandte Chemie International Edition. 2013-02-18, 52 (8): 2231–2234 [2020-12-29]. doi:10.1002/anie.201207803 （英语）.