MIL-53

MIL-53
别名	MIL-53(Cr)
识别
缩写	MIL-53(Cr)
CAS号	442912-79-0（无水） ; 477890-83-8（一水合物） ; 477890-84-9（一DMF合物）
性质
化学式	C8H5CrO5
外观	固体
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

MIL-53是一种金属有机框架材料，名称中字母缩写MIL为Matériaux de l′Institut Lavoisier，它由圣康丁昂伊夫利纳-凡尔赛大学拉瓦锡研究所的Gérard Férey组所合成。^[1]目前已知其它三价金属的类似物，如Al^[2]、Fe^[3]等。不同种类的MIL-53材料按下述区分：MIL-53as（as = as synthesized（合成原态），使用了对苯二甲酸）、MIL-53lt（lt = low temperature（低温），低温改性）和MIL-53ht（ht = high temperature（高温），高温改性）。

参考文献

^ Serre, Christian; Millange, Franck; Thouvenot, Christelle; Noguès, Marc; Marsolier, Gérard; Louër, Daniel; Férey, Gérard. Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or Cr III (OH)·{O 2 C−C 6 H 4 −CO 2 }·{HO 2 C−C 6 H 4 −CO 2 H} x ·H 2 O y. Journal of the American Chemical Society. 2002-11-01, 124 (45). ISSN 0002-7863. doi:10.1021/ja0276974 （英语）.
^ Loiseau, Thierry; Serre, Christian; Huguenard, Clarisse; Fink, Gerhard; Taulelle, Francis; Henry, Marc; Bataille, Thierry; Férey, Gérard. A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration. Chemistry - A European Journal. 2004-03-19, 10 (6). ISSN 0947-6539. doi:10.1002/chem.200305413 （英语）.
^ Horcajada, Patricia; Serre, Christian; Maurin, Guillaume; Ramsahye, Naseem A.; Balas, Francisco; Vallet-Regí, María; Sebban, Muriel; Taulelle, Francis; Férey, Gérard. Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery. Journal of the American Chemical Society. 2008-05-01, 130 (21) [2022-10-01]. ISSN 0002-7863. doi:10.1021/ja710973k. （原始内容存档于2022-10-06）（英语）.

参见

金属有机框架材料（MOF）

[Serre-1] Serre, Christian; Millange, Franck; Thouvenot, Christelle; Noguès, Marc; Marsolier, Gérard; Louër, Daniel; Férey, Gérard. Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or Cr III (OH)·{O 2 C−C 6 H 4 −CO 2 }·{HO 2 C−C 6 H 4 −CO 2 H} x ·H 2 O y. Journal of the American Chemical Society. 2002-11-01, 124 (45). ISSN 0002-7863. doi:10.1021/ja0276974 （英语）.

[2] Loiseau, Thierry; Serre, Christian; Huguenard, Clarisse; Fink, Gerhard; Taulelle, Francis; Henry, Marc; Bataille, Thierry; Férey, Gérard. A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL-53) Upon Hydration. Chemistry - A European Journal. 2004-03-19, 10 (6). ISSN 0947-6539. doi:10.1002/chem.200305413 （英语）.

[3] Horcajada, Patricia; Serre, Christian; Maurin, Guillaume; Ramsahye, Naseem A.; Balas, Francisco; Vallet-Regí, María; Sebban, Muriel; Taulelle, Francis; Férey, Gérard. Flexible Porous Metal-Organic Frameworks for a Controlled Drug Delivery. Journal of the American Chemical Society. 2008-05-01, 130 (21) [2022-10-01]. ISSN 0002-7863. doi:10.1021/ja710973k. （原始内容存档于2022-10-06）（英语）.

[1]

[2]

[3]