二烴基硼酸

二烴基硼酸是硼酸的兩個羥基被烴基取代得到的有機硼化合物，其通式為R₂BOH。它的羥基氫被烴基取代，可以得到二烴基硼酸酯（R₂BOR'）。

二烴基硼酸及其衍生物

常見的物質見列表：

R₂BOR'	酸 R'=H	酸酐	酯R'
R	氫（H）	氧（-O-）	氨基乙基	乙基	正丙基	正丁基	3-甲基丙基	1-甲基丙基	苯基	乙二氧二基	甲基	8-喹啉基
苯基	Y	^[1]	Y cas 524-95-8	Y cas 43185-52-0	Y	Y cas 15323-04-3	Y	Y	Y		Y cas 13471-36-8	SID 535455
o-甲苯基			Y				Y
m-甲苯基			Y
p-甲苯基	Y^[2]		Y
p-茴香基	Y	Y^[3]	Y
p-聯苯基	Y	Y^[4]	Y
p-氯苯基	Y cas 89566-59-6	Y^[5]	Y cas 61733-90-2								Y cas 564483-61-0
3-氯苯基	Y cas 433338-06-8
α-萘基	Y	Y^[6]	Y^[7] cas 6962-88-5
β-萘基	Y	Y^[3]
p-溴苯基	Y	Y^[3]	Y^[8]
2-甲基-5-氯苯基	Y	Y^[5]
2-噻吩基			^[9] SID 3881207									SID 8142470
mesityl	sid 4278417 CAS 20631-84-9^[10]^[11]^[12]
甲基	Y cas 13061-97-7			Y cas 86610-16-4							Y cas 4443-43-0
乙基	Y cas 4426-31-7	Y^[13] 7318-84-5									Y cas 7397-46-8
烯丙基						Y
正丁基	Y cas 1189-31-7	Y^[14]	cas 19324-14-2		Y cas 2344-21-0	Y	Y	Y	Y	Y	Y cas 2344-21-0
4-甲基丁基									Y
2-氯乙烯基	Y	Y^[15]
3,5-二甲基苯基	Y^[16]
丙基				Y cas 53678-60-7							Y cas 2938-89-8
1-甲基丙基		cas 4026-69-1
2-甲基丙基		cas 4026-82-8

參考文獻

^ Lange, Thomas; Böhme, Uwe; Roewer, Gerhard. Crystal structure of tetraphenyldiboroxane a monomer diboroxane. Inorganic Chemistry Communications. 2002, 5 (6): 377–379. doi:10.1016/S1387-7003(02)00402-1.
^ Erbes, Michael; Klaus Forstinger; Andreas Meudt. Process for preparing boronic and borinic acids. US Patent 20020161230. 31 Oct 2002 [15 October 2013]. （原始內容存檔於2016-03-06）.
^ ^3.0 ^3.1 ^3.2 Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 24
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 25
^ ^5.0 ^5.1 Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 26
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 5
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 9
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 2
^ Low, John Nicolson; Musgrave, Oliver; Wardell, James. (2-Aminoethoxy)bis(2-thienyl)boron. Acta Crystallographica Section C. 15 February 2000, 56 (2): e63. doi:10.1107/S0108270100000482.
^ Birch, Samuel J.; Boss, Sally R.; Cole, Sarah C.; Coles, Martyn P.; Haigh, Robert; Hitchcock, Peter B.; Wheatley, Andrew E. H. The structural characteristics of organozinc complexes incorporating N,N?-bidentate ligands. Dalton Transactions. 1 January 2004, (21): 3568–3574. PMID 15510278. doi:10.1039/B410945G.
^ Kuhlmann, Matthias; Baumgartner, Thomas; Parvez, Masood. A new polymorph of dimesitylborinic acid. Acta Crystallographica Section E. 7 June 2008, 64 (7): o1185. PMC 2961869 . PMID 21202827. doi:10.1107/S1600536808015638.
^ Weese, Kenneth J.; Bartlett, Ruth A.; Murray, Brendan D.; Olmstead, Marilyn M.; Power, Philip R. Synthesis and spectroscopic and structural characterization of derivatives of the quasi-alkoxide ligand [OBMes2]- (Mes = 2,4,6-Me3C6H2). Inorganic Chemistry. 1 July 1987, 26 (15): 2409–2413. doi:10.1021/ic00262a015.
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 28
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 17
^ Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 29
^ Winkle, D. boronic acids can be used as viable alternatives to borinic acids in suzuki coupling reactions. Organic Process Research & Development. 2001, 5 (4): 450–451. doi:10.1021/op010207s. ^{[失效連結]}

[1] Lange, Thomas; Böhme, Uwe; Roewer, Gerhard. Crystal structure of tetraphenyldiboroxane a monomer diboroxane. Inorganic Chemistry Communications. 2002, 5 (6): 377–379. doi:10.1016/S1387-7003(02)00402-1.

[Erbes-2] Erbes, Michael; Klaus Forstinger; Andreas Meudt. Process for preparing boronic and borinic acids. US Patent 20020161230. 31 Oct 2002 [15 October 2013]. （原始內容存檔於2016-03-06）.

[ufdcimages.uflib.ufl.edu-3] 3.0 ^3.1 ^3.2 Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 24

[4] Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 25

[http-5] 5.0 ^5.1 Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 26

[6] Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 5

[7] Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 9

[8] Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 2

[9] Low, John Nicolson; Musgrave, Oliver; Wardell, James. (2-Aminoethoxy)bis(2-thienyl)boron. Acta Crystallographica Section C. 15 February 2000, 56 (2): e63. doi:10.1107/S0108270100000482.

[10] Birch, Samuel J.; Boss, Sally R.; Cole, Sarah C.; Coles, Martyn P.; Haigh, Robert; Hitchcock, Peter B.; Wheatley, Andrew E. H. The structural characteristics of organozinc complexes incorporating N,N?-bidentate ligands. Dalton Transactions. 1 January 2004, (21): 3568–3574. PMID 15510278. doi:10.1039/B410945G.

[11] Kuhlmann, Matthias; Baumgartner, Thomas; Parvez, Masood. A new polymorph of dimesitylborinic acid. Acta Crystallographica Section E. 7 June 2008, 64 (7): o1185. PMC 2961869 . PMID 21202827. doi:10.1107/S1600536808015638.

[12] Weese, Kenneth J.; Bartlett, Ruth A.; Murray, Brendan D.; Olmstead, Marilyn M.; Power, Philip R. Synthesis and spectroscopic and structural characterization of derivatives of the quasi-alkoxide ligand [OBMes2]- (Mes = 2,4,6-Me3C6H2). Inorganic Chemistry. 1 July 1987, 26 (15): 2409–2413. doi:10.1021/ic00262a015.

[13] Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 28

[14] Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 17

[15] Povlock, Thomas Paul. Boroxines: Their Reactions and Ring Stability (PDF). August 1960 [5 October 2013]. （原始內容 (PDF)存檔於2016-03-05）. ref 29

[16] Winkle, D. boronic acids can be used as viable alternatives to borinic acids in suzuki coupling reactions. Organic Process Research & Development. 2001, 5 (4): 450–451. doi:10.1021/op010207s. ^{[失效連結]}

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