N-甲基己胺

N-甲基己胺
识别
CAS号	35161-70-7
性质
化学式	C7H17N
摩尔质量	115.22 g·mol−1
密度	0.761 g·cm−3（20 °C）
沸点	135 °C（408 K）
	若非注明，所有数据均出自标准状态（25 ℃，100 kPa）下。

N-甲基己胺是一种有机化合物，化学式为C₇H₁₇N。它可由甲胺、次氯酸钠和二甲基正己基硼（或三己基硼^[3]）反应制得。^[4]它和亚硝酸钠在甲磺酸-氧化铝催化下反应，可以得到N-亚硝基-N-甲基己胺。^[5]它和溴化氰反应，可以得到N-氰基-N-甲基己胺。^[6]

参考文献

^ Loffler, Karl. Formation of N-Alkyl Pyrrolidines. Berichte der Deutschen Chemischen Gesellschaft, 1910. 43: 2035-2048. ISSN 0365-9496.
^ Emmanuel Yankep, Henriette Kapnang, Georges Charles. Alkylaminomethylation d'organomagnesiens. Tetrahedron Letters. 1989-01, 30 (52): 7383–7384 [2022-02-22]. doi:10.1016/S0040-4039(00)70703-9. （原始内容存档于2018-06-08）（英语）.
^ George W. Kabalka, Zhe Wang. Reaction of trialkylboranes with alkylamines: synthesis of dialkylamines. Organometallics. 1989-04, 8 (4): 1093–1095 [2022-02-22]. ISSN 0276-7333. doi:10.1021/om00106a034. （原始内容存档于2022-02-22）（英语）.
^ George W. Kabalka, Zhe Wang. Preparation of Isomerically Pure Dialkylamines via the Reaction of Dimethylalkylboranes with Chloroalkylamine. Synthetic Communications. 1990-01, 20 (2): 231–237 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397919008052288 （英语）.
^ Khodabakhsh Niknam, Mohammad Ali Zolfigol. Alumina–Methanesulfonic Acid (AMA)/NaNO 2 as an Efficient Procedure for the Chemoselectivite N‐Nitrosation of Secondary Amines. Synthetic Communications. 2006-08, 36 (16): 2311–2319 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397910600639927 （英语）.
^ Toru Hashimoto, Satoshi Ishii, Reiko Yano, Hiroki Miura, Ken Sakata, Ryo Takeuchi. Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Cyanamides. Advanced Synthesis & Catalysis. 2015-12-14, 357 (18): 3901–3916 [2022-02-22]. doi:10.1002/adsc.201500637. （原始内容存档于2022-02-22）（英语）.

[1] Loffler, Karl. Formation of N-Alkyl Pyrrolidines. Berichte der Deutschen Chemischen Gesellschaft, 1910. 43: 2035-2048. ISSN 0365-9496.

[2] Emmanuel Yankep, Henriette Kapnang, Georges Charles. Alkylaminomethylation d'organomagnesiens. Tetrahedron Letters. 1989-01, 30 (52): 7383–7384 [2022-02-22]. doi:10.1016/S0040-4039(00)70703-9. （原始内容存档于2018-06-08）（英语）.

[3] George W. Kabalka, Zhe Wang. Reaction of trialkylboranes with alkylamines: synthesis of dialkylamines. Organometallics. 1989-04, 8 (4): 1093–1095 [2022-02-22]. ISSN 0276-7333. doi:10.1021/om00106a034. （原始内容存档于2022-02-22）（英语）.

[4] George W. Kabalka, Zhe Wang. Preparation of Isomerically Pure Dialkylamines via the Reaction of Dimethylalkylboranes with Chloroalkylamine. Synthetic Communications. 1990-01, 20 (2): 231–237 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397919008052288 （英语）.

[5] Khodabakhsh Niknam, Mohammad Ali Zolfigol. Alumina–Methanesulfonic Acid (AMA)/NaNO 2 as an Efficient Procedure for the Chemoselectivite N‐Nitrosation of Secondary Amines. Synthetic Communications. 2006-08, 36 (16): 2311–2319 [2022-02-22]. ISSN 0039-7911. doi:10.1080/00397910600639927 （英语）.

[6] Toru Hashimoto, Satoshi Ishii, Reiko Yano, Hiroki Miura, Ken Sakata, Ryo Takeuchi. Iridium-Catalyzed [2+2+2] Cycloaddition of α,ω-Diynes with Cyanamides. Advanced Synthesis & Catalysis. 2015-12-14, 357 (18): 3901–3916 [2022-02-22]. doi:10.1002/adsc.201500637. （原始内容存档于2022-02-22）（英语）.

[1]

[2]

[3]

[4]

[5]

[6]